Delrin® Homopolymer Acetal compared with Acetal Copolymer
Many of our clients assume that Delrin® rod and Acetal rod are the same thing. This is not true.
Yes, all Dupont Delrin® rod is Homopolymer Acetal rod, but not all Acetal rod is Delrin® rod.
Delrin® is the trade name for Homopolymer Acetal made by Dupont. Dupont™ Delrin ® is a popular acetal homopolymer brand name and the most commonly used acetal homopolymer.
This is the most recognized of all trade names for Acetal materials, but not the only available Acetal material. The Copolymer Acetal resin is produced by a wide variety of large plastic manufacturers, BASF is probably one of the largest and most well known. Some main resin names are: BASF Ultraform® H4320, Kepital® F10-02, Hostaform® M25 and many others.
While Delrin® Homopolymer Acetal is a wonderful material, in a larger cross sections Homopolymer can exhibit center line porosity, or ‘soft centers’. This can sometimes be seen with the naked eye, and is a darker white in a normally milky white natural colored material. This center line porosity can cause problems in some applications. This porosity can cause leakage of fluid if under pressure, or soft center’s of homopolymer rod and sheet.
This should not stop you from considering Delrin® Homopolymer Acetal though. Many other properties of the homopolymer resins are superior to the copolymer resins. These properties are:
General Property
ASTM Test
Typical Value Unfilled Homo-Polymer
Typical Value Unfilled Co-Polymer
Specific Gravity
D792
1.42
1.40
Tensile Strength Yield
D638
9,600 – 11,000
9,000 – 10,200
Tensile Modulus
D638
450,000
400,000
Izod Impact – Notched
D256
1.2
1.0
Hardness – Rockwell
D785
M94
M90
Deflection Temp @ 264psi
D648
257
220
Deflection Temp @ 66 psi
D648
347
335
Water Absorption @ 24 hrs
%
0.24
0.25
Co. Thermal Expansion
D696
6.83X10-5
5.4X10-5
Some key properties for homopolymer acetal are: higher tensile strength, increased Izod impact, higher deflection temperatures and it is slightly harder. The co-efficient of thermal expansion is a bit higher, and needs to be considered when designing a new part. Extruded Delrin® brand homopolymer resin material also comes in several resin variations, including: Delrin® 150 and Delrin® 507, contact us for details. Dupont™ Delrin® is a popular acetal homopolymer brand name and the most commonly used acetal homopolymer.
Many of our clients prefer the homopolymer rod and sheet for small machined parts. This is due to the increase in a few key properties, and of course brand recognition. Some of our major brand names for quality Copolymer Acetal (POM-C) sheet and Rod include: Tecaform AH®, Sustarin C®, ZL 900® and Pomalux®.
Both resins meet the standard ASTM-D-6778, and the cancelled specs, L-P-395 and ASTM-D-4181. Contact us for certification and specifications you may require.
The Acetal family of plastic resins are excellent for wear resistance, great mechanical strength, and superior machining properties. It is available in a huge range of sizes and shapes. Click here for more details on Acetal – Homopolymer Acetal Rod, and sometimes referred to as plastic dowel. We also have the capacity to supply colored Acetal Copolymer or Delrin® Homopolymer Acetal rod; click here from more details on the colored Acetal material.
Similar materials to Acetal Copolymer – Homopolymer Acetal are Nylon Rod, PET Rod and Noryl® Rod. Most materials are available as round rod, square rod, bar, strip, sheet and plate.
Please contact us for more details on these and other plastic materials. For a comparison chart of plastic materials click here: Plastic Materials Selection Guide
**Note: Delrin® is a registered Trademark of Dupont
Acetal Copolymer and ABS (Acrylonitrile-Butadiene-Stryene) have some similar properties but are really very different materials. They similarities are: high impact strength, ease of machining with standard cutting tools and good mechanical properties. They are also both FDA compliant and are both good substitutes for brass. They also have great water absorption resistance and good electrical properties. Both materials are good for some of the same applications but certainly not all. Listed below are some of the major differences.
ABS Sheet and Rod Information
ABS comes as Natural (straw) and Black color in Plate, Slab, Sheets and Rods, and thin sheet (.040″ – .250″) it is available as White or Black with a textured surface one side. It can be cut from 48″ X 96″ sheets into strip, panels or pieces.
ABS is formable. ABS is a great thermo-formable material while Acetal is not. Acetal is used more for machined parts such as gears and screws. ABS is great for molding and shaping parts from vacuum to heat forming. Excellent for model building and prototype projects.
ABS is easily bondable (similar to PVC). ABS can be bonded or welded to itself. Because Acetal is self lubricating, it is not possible for anything to stick to it unless etching is done – therefor it is not bondable.
ABS is a great material for painting and silk screening. While Acetal can not be painted or silk screened unless it has undergone Corona Treating (a flame surface treatment), but if treated will nice paint or screened surface.
ABS has better chemical resistance than Acetals. Both are attacked by acids like sulfuric, but ABS has a wider range of resistance to chemicals like aqueous acids, alkaline and alcohol. Acetal will degrade when exposed to such chemicals as chlorine and alkaline.
Specialty grades of ABS are available, including: Glass Filled, Static Dissipating, and Fire Retardant Grades (like Royalite – R59)
ABS Typical Properties Table
General Property
ASTM Test
Value
Specific Gravity
D7921
1.08 – 1.25
Tensile Strength
Yield D638
4,100
Izod Impact – Notched
D256
7.7
Hardness – Rockwell
D785
R105
Deflection Temp @ 264psi
D648
177
Co. Thermal Expansion
D696
5.3X10-54.6 -5.5X10-5
Acetal Copolymer and Homopolymer Sheet and Rod Information
ABS Resin Structure
Acetal is the better machining plastic, considered the best machining plastic material. Because of its durability and wear resistance, Acetal is an excellent choice for producing a wide variety of parts that require high wear resistance over a wide period of time. When machining to tight and specific tolerances, Acetal is ideal.
Acetal has low co-efficient of friction. Due to its self lubricating properties, it is a great material for sliding and wear applications. This material provides years of maintenance free bushings and bearings.
Acetal sheet is produced from .062″ – over 6″ thick and sheet sizes of up to 48″ X 120″ as standard. The standard color for Acetal and Delrin is Natural (a deep milky white) and Black. Some colors are available as Medical Grade, and can be obtained in limited sizes. These sheet are available cut to: slabs, blocks, plates, slabs and blocks.
Acetal (Polyoxymethylene) can be both a homopolymer and a copolymer. The homopolymer acetal has a repeating chain of one atom while the Acetal copolymer has two atoms forming a repeating chain. Dupont™ Delrin® is a popular acetal homopolymer brand name and the most commonly used acetal homopolymer.
Acetal – Delrin Properties Table
General Property
ASTM Test
Typical Value Unfilled Homo-Polymer
Typical Value Unfilled Co-Polymer
Specific Gravity
D792
1.42
1.40
Tensile Strength Yield
D638
9,600 – 11,000
9,000 – 10,200
Tensile Modulus
D638
450,000
400,000
Izod Impact – Notched
D256
1.2
1.0
Hardness – Rockwell
D785
M94
M90
Deflection Temp @ 264psi
D648
257
220
Deflection Temp @ 66 psi
D648
347
335
Water Absorption @ 24 hrs
%
0.24
0.25
Co. Thermal Expansion
D696
6.83X10-5
5.4X10-5
ABS and Acetal – Similar, but very different materials
Both of these materials possess excellent qualities and have a wide range of different uses. Acetal is great for machining, while ABS is great for forming and bonding. They both can be used for machined parts and are great choices for food contact and electrical applications. These two materials are both strong and durable plastics, but one might be better than the other for a specific job. When picking the right plastic, it is important to compare plastics and their specific properties to make sure the material won’t fail and that your job will be successful.
Contact us for additional information, call us at 866-832-9315 or contact us here. Consider Industrial Plastic Supply for all your plastic needs, we want to be your go-to plastic supplier.
**Note: Delrin® is a registered Trademark of Dupont
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